BIBLIOS

Document type
Journal articles

Document subtype
Full paper

Title
P, ρ, and T Measurements of the Limonene + α-Pinene Mixtures

Participants in the publication
Elisa Langa (Author)
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA
Antonio F. Palavra (Author)
INSTITUTO SUPERIOR TÉCNICO
Carlos A. Nieto de Castro (Author)
Dep. Química e Bioquímica
CQE
Ana M. Mainar (Author)

Summary
The density of the binary system 1-methyl-4-(1-methylethenyl)-cyclohexene (limonene) + (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene (α-pinene) has been measured for nine different compositions and the pure components at five pressures from (20.0 to 40.0) MPa and six temperatures from (283.15 to 358.15) K with a vibrating-tube densimeter. The experimental uncertainty is estimated to be ± 0.5 kg·m−3. The isothermal compressibility and isobaric thermal expansion were derived from the experimental density data. Two different equations of state, conventional SAFT and PC-SAFT, were applied to predict the densities of the mixture. The best predictions were achieved with PC-SAFT.


Institution
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Where published
Journal of Chemical & Engineering Data

Publication Identifiers

Publisher
American Chemical Society (ACS)



Document Identifiers
DOI - https://doi.org/10.1021/je1009619
URL - http://dx.doi.org/10.1021/je1009619

Keywords
α-pinene limonene terpenos density isothermal compressibility isobaric thermal expansion SAFT

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