BIBLIOS

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
P, ρ, and T Measurements of the Limonene + α-Pinene Mixtures

Participantes na publicação
Elisa Langa (Author)
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA
Antonio F. Palavra (Author)
INSTITUTO SUPERIOR TÉCNICO
Carlos A. Nieto de Castro (Author)
Dep. Química e Bioquímica
CQE
Ana M. Mainar (Author)

Resumo
The density of the binary system 1-methyl-4-(1-methylethenyl)-cyclohexene (limonene) + (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene (α-pinene) has been measured for nine different compositions and the pure components at five pressures from (20.0 to 40.0) MPa and six temperatures from (283.15 to 358.15) K with a vibrating-tube densimeter. The experimental uncertainty is estimated to be ± 0.5 kg·m−3. The isothermal compressibility and isobaric thermal expansion were derived from the experimental density data. Two different equations of state, conventional SAFT and PC-SAFT, were applied to predict the densities of the mixture. The best predictions were achieved with PC-SAFT.


Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
Journal of Chemical & Engineering Data

Identificadores da Publicação

Editora
American Chemical Society (ACS)



Identificadores do Documento
DOI - https://doi.org/10.1021/je1009619
URL - http://dx.doi.org/10.1021/je1009619

Keywords
α-pinene limonene terpenos density isothermal compressibility isobaric thermal expansion SAFT

Download