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Publication details

Document type
Journal articles

Document subtype
Full paper

Title
Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents

Participants in the publication
Raquel M. C. Gonçalves (Author)
Lídia M. P. C. Albuquerque (Author)
Filomena E. L. Martins (Author)
Dep. Química e Bioquímica
 Ana M. N. Simões (Author)
Joaquim J. Moura Ramos (Author)

Summary
The application of cavity theories of solution and linear solvation energy relationships to the interpretation of enthalpy of solution values of tert?butyl halides in hydroxylic media, measured at 25 °C and infinite dilution, is deserted, in order to define the intermolecular forces acting between solutes and solvents. It is concluded that solvent dipolarity and solvent HBD acidity effects dominate the solution process. An empirical equation relating the enthalpies of solution with selected properties of both solvents and solutes is proposed. New experimental Δ Hs∞ values for tert?butyl iodide in 13 alcohols are reported.

Date of Publication
1992-02

Institution
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Where published
Journal of Physical Organic Chemistry

Publication Identifiers

Publisher
John Wiley & Sons Ltd.

Volume
5
Number
2

Number of pages
8
Starting page
93
Last page
100

Document Identifiers
DOI - https://doi.org/10.1002/poc.610050205
URL - http://dx.doi.org/10.1002/poc.610050205


Export

APA
Raquel M. C. Gonçalves, Lídia M. P. C. Albuquerque, Filomena E. L. Martins, Ana M. N. Simões, Joaquim J. Moura Ramos, (1992). Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents. Journal of Physical Organic Chemistry, 5, 93-100. http://dx.doi.org/10.1002/poc.610050205

IEEE
Raquel M. C. Gonçalves, Lídia M. P. C. Albuquerque, Filomena E. L. Martins, Ana M. N. Simões, Joaquim J. Moura Ramos, "Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents" in Journal of Physical Organic Chemistry, vol. 5, pp. 93-100, 1992. 10.1002/poc.610050205

BIBTEX
@article{50262, author = {Raquel M. C. Gonçalves and Lídia M. P. C. Albuquerque and Filomena E. L. Martins and Ana M. N. Simões and Joaquim J. Moura Ramos}, title = {Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents}, journal = {Journal of Physical Organic Chemistry}, year = 1992, pages = {93-100}, volume = 5 }