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Detalhes Referência

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents

Participantes na publicação
Raquel M. C. Gonçalves (Author)
Lídia M. P. C. Albuquerque (Author)
Filomena E. L. Martins (Author)
Dep. Química e Bioquímica
 Ana M. N. Simões (Author)
Joaquim J. Moura Ramos (Author)

Resumo
The application of cavity theories of solution and linear solvation energy relationships to the interpretation of enthalpy of solution values of tert?butyl halides in hydroxylic media, measured at 25 °C and infinite dilution, is deserted, in order to define the intermolecular forces acting between solutes and solvents. It is concluded that solvent dipolarity and solvent HBD acidity effects dominate the solution process. An empirical equation relating the enthalpies of solution with selected properties of both solvents and solutes is proposed. New experimental Δ Hs∞ values for tert?butyl iodide in 13 alcohols are reported.

Data de Publicação
1992-02

Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
Journal of Physical Organic Chemistry

Identificadores da Publicação

Editora
John Wiley & Sons Ltd.

Volume
5
Fascículo
2

Número de Páginas
8
Página Inicial
93
Página Final
100

Identificadores do Documento
DOI - https://doi.org/10.1002/poc.610050205
URL - http://dx.doi.org/10.1002/poc.610050205


Exportar referência

APA
Raquel M. C. Gonçalves, Lídia M. P. C. Albuquerque, Filomena E. L. Martins, Ana M. N. Simões, Joaquim J. Moura Ramos, (1992). Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents. Journal of Physical Organic Chemistry, 5, 93-100. http://dx.doi.org/10.1002/poc.610050205

IEEE
Raquel M. C. Gonçalves, Lídia M. P. C. Albuquerque, Filomena E. L. Martins, Ana M. N. Simões, Joaquim J. Moura Ramos, "Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents" in Journal of Physical Organic Chemistry, vol. 5, pp. 93-100, 1992. 10.1002/poc.610050205

BIBTEX
@article{50262, author = {Raquel M. C. Gonçalves and Lídia M. P. C. Albuquerque and Filomena E. L. Martins and Ana M. N. Simões and Joaquim J. Moura Ramos}, title = {Enthalpies of solution and intermolecular forces.tert-butyl halides in hydroxylic solvents}, journal = {Journal of Physical Organic Chemistry}, year = 1992, pages = {93-100}, volume = 5 }