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Publication details

Document type
Journal articles

Document subtype
Full paper

Title
Solvent Effects on Solution Enthalpies of Adamantyl Derivatives. A Multiparametric Approach

Participants in the publication
F. Martins (Author)
Dep. Química e Bioquímica
 CQB
 L. Moreira (Author)
N. Nunes (Author)
R. E. Leitão (Author)

Summary
Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving δcav h s as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes’ characteristics. New insights on the solution processes under scrutiny are presented.

Date of Submisson/Request
2008-10-03
Date of Acceptance
2009-03-19
Date of Publication
2010-01-13

Institution
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Where published
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY

Publication Identifiers
ISSN - 1388-6150

Publisher
Springer

Collection
Portuguese Special Chapter

Volume
100

Number of pages
9
Starting page
483
Last page
491

Document Identifiers
DOI - https://doi.org/10.1007/s10973-009-0651-x

Rankings
SCIMAGO Q3 (2010) - 0.474 - Physical and Theoretical Chemistry
Web Of Science Q3 (2010) - 1.752 - Physical Chemistry

Keywords
1-Bromoadamantane 1-Adamantanol 2-Adamantanone Solution enthalpy Multiparametric equation Solvent effects


Export

APA
F. Martins, L. Moreira, N. Nunes, R. E. Leitão, (2010). Solvent Effects on Solution Enthalpies of Adamantyl Derivatives. A Multiparametric Approach. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 100, 483-491. ISSN 1388-6150. eISSN .

IEEE
F. Martins, L. Moreira, N. Nunes, R. E. Leitão, "Solvent Effects on Solution Enthalpies of Adamantyl Derivatives. A Multiparametric Approach" in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, vol. 100, pp. 483-491, 2010. 10.1007/s10973-009-0651-x

BIBTEX
@article{24853, author = {F. Martins and L. Moreira and N. Nunes and R. E. Leitão}, title = {Solvent Effects on Solution Enthalpies of Adamantyl Derivatives. A Multiparametric Approach}, journal = {JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY}, year = 2010, pages = {483-491}, volume = 100 }