BIBLIOS

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
Solvent Effects on Solution Enthalpies of Adamantyl Derivatives. A Multiparametric Approach

Participantes na publicação
F. Martins (Author)
Dep. Química e Bioquímica
CQB
L. Moreira (Author)
N. Nunes (Author)
R. E. Leitão (Author)

Resumo
Solution enthalpies of 1-bromoadamantane, 1-adamantanol, and 2-adamantanone in a large set of protic and aprotic solvents are reported at 298.15 K. Solvent effects on the solution processes of these solutes are analyzed in terms of a modified TAKA equation, involving δcav h s as the cavity term. The nature and magnitude of the major interactions which influence these processes are assessed and discussed in terms of the solutes’ characteristics. New insights on the solution processes under scrutiny are presented.


Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY

Identificadores da Publicação
ISSN - 1388-6150

Editora
Springer

Coleção
Portuguese Special Chapter



Identificadores do Documento
DOI - https://doi.org/10.1007/s10973-009-0651-x

Identificadores de Qualidade
SCIMAGO Q3 (2010) - 0.474 - Physical and Theoretical Chemistry
Web Of Science Q3 (2010) - 1.752 - Physical Chemistry

Keywords
1-Bromoadamantane 1-Adamantanol 2-Adamantanone Solution enthalpy Multiparametric equation Solvent effects