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Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
[C2mim][CH3SO3]?A Suitable New Heat Transfer Fluid? Part 2: Thermophysical Properties of Its Mixtures with Water

Participantes na publicação
Francisco E. B. Bioucas (Author)
CQE
Carla S. G. P. Queirós (Author)
CQE
Daniel Lozano-Martín (Author)
UNIVERSIDADE DE VALLADOLID
M. S. Ferreira (Author)
Xavier Paredes (Author)
Dep. Química e Bioquímica
CQE
Ângela F. Santos (Author)
Dep. Química e Bioquímica
CQE
Fernando J. V. Santos (Author)
Dep. Química e Bioquímica
CQE
Manuel L. M. Lopes (Author)
Dep. Química e Bioquímica
CQE
Isabel M. S. Lampreia (Author)
Dep. Química e Bioquímica
CQE
Maria José V. Lourenço (Author)
Dep. Química e Bioquímica
CQE
Carlos A. Nieto de Castro (Author)
Dep. Química e Bioquímica
CQE
Klemens Massonne (Author)
BASF AG

Resumo
Ionic liquids have proved to be excellent heat transfer fluids and alternatives to common HTF’s used in industry for heat exchangers and other heat transfer equipment. However, its industrial utilization depends on the cost/kg of its production, to be competitive for industrial applications with biphenyl and diphenyl oxide, alkylated aromatics and dimethyl polysiloxane oils, which degrade above 200ºC and possess some environmental problems. The efficiency of a heat transfer fluid depends on the fundamental thermophysical properties influencing convective heat transfer (density, heat capacity, thermal conductivity, and viscosity), as these properties are necessary to calculate the heat transfer coefficients for different heat exchanger geometries.\\nIn part 1, the thermophysical properties of pure 1-ethyl-3-methylimidazolium methanesulfonate [C2mim][CH3SO3] (CAS no. 145022-45-3), (ECOENG™ 110), produced by BASF, under the trade name of Basionics® ST35, with an assay ≥ 97% with ≤ 0.5% water and ≤ 2% chloride (Cl-), were presented, for temperatures slightly below room temperature and up to 355 K. \\nIn this paper we report the thermophysical properties of mixtures of [C2mim][CH3SO3] with water, in the whole concentration range, at P = 0.1 MPa. The properties measured were density and speed of sound (293.15 < T/K < 343.15), viscosity, electrical, thermal conductivity and refractive index (293.15 < T/K < 353.15), and infinite dilution diffusion coefficient of the ionic liquid in water (298.15 K).\\nProperties for the mixture like the isobaric expansion coefficient, the isentropic compressibility, apparent molar volumes, apparent molar isentropic compressions, and the thermodynamic excess properties, like excess molar volume, excess molar isobaric expansion and isentropic compression, excess viscosity, molar refraction, and infinite dilution diffusion coefficients of the cation, the anion and other common anions in ionic liquids were obtained, within this temperature range. The validity of the Walden relation for this ionic liquid was also determined. This amount of experimental information, in addition to recent molecular simulation studies available in the literature permit a clear picture of the structure of these binary mixtures, the influence of composition and temperature, paving the way to a technological discussion of the possible application of these mixtures as new heat transfer fluids or battery electrolytes.

Editor
Phillip E. Savage,

Data de Submissão/Pedido
2021-07-24
Data de Aceitação
2022-01-18
Data de Publicação
2022-01-27

Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
Industrial & Engineering Chemistry Research

Identificadores da Publicação
ISSN - 0888-5885

Local
Washington, USA

Editora
American Chemical Society (ACS)

Volume
61
Fascículo
5

Número de Páginas
26
Página Inicial
2280
Página Final
2305

Identificadores do Documento
DOI - https://doi.org/10.1021/acs.iecr.1c02970
URL - http://dx.doi.org/10.1021/acs.iecr.1c02970

Identificadores de Qualidade
SCIMAGO Q1 (2021) - 6 - Chemical Engineering
Google Metrics (2021) - 73 - Chemical and Materials Sciences
SCIMAGO Q1 (2021) - 0.878 - Chemical Engineering

Keywords
1-ethyl-3-methylimidazolium methanesulfonate water Basionics® ST35 ECOENG™ 110 binary mixtures density speed of sound refractive index viscosity electrical conductivity thermal conductivity infinite dilution diffusion coefficient excess properties heat transfer

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APA
Francisco E. B. Bioucas, Carla S. G. P. Queirós, Daniel Lozano-Martín, M. S. Ferreira, Xavier Paredes, Ângela F. Santos, Fernando J. V. Santos, Manuel L. M. Lopes, Isabel M. S. Lampreia, Maria José V. Lourenço, Carlos A. Nieto de Castro, Klemens Massonne, (2022). [C2mim][CH3SO3]?A Suitable New Heat Transfer Fluid? Part 2: Thermophysical Properties of Its Mixtures with Water. Industrial & Engineering Chemistry Research, 61, 2280-2305. ISSN 0888-5885. eISSN . http://dx.doi.org/10.1021/acs.iecr.1c02970

IEEE
Francisco E. B. Bioucas, Carla S. G. P. Queirós, Daniel Lozano-Martín, M. S. Ferreira, Xavier Paredes, Ângela F. Santos, Fernando J. V. Santos, Manuel L. M. Lopes, Isabel M. S. Lampreia, Maria José V. Lourenço, Carlos A. Nieto de Castro, Klemens Massonne, "[C2mim][CH3SO3]?A Suitable New Heat Transfer Fluid? Part 2: Thermophysical Properties of Its Mixtures with Water" in Industrial & Engineering Chemistry Research, vol. 61, pp. 2280-2305, 2022. 10.1021/acs.iecr.1c02970

BIBTEX
@article{54165, author = {Francisco E. B. Bioucas and Carla S. G. P. Queirós and Daniel Lozano-Martín and M. S. Ferreira and Xavier Paredes and Ângela F. Santos and Fernando J. V. Santos and Manuel L. M. Lopes and Isabel M. S. Lampreia and Maria José V. Lourenço and Carlos A. Nieto de Castro and Klemens Massonne}, title = {[C2mim][CH3SO3]?A Suitable New Heat Transfer Fluid? Part 2: Thermophysical Properties of Its Mixtures with Water}, journal = {Industrial & Engineering Chemistry Research}, year = 2022, pages = {2280-2305}, volume = 61 }