BIBLIOS

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
P, ρ, and T measurements of the (limonene+β-pinene) mixtures

Participantes na publicação
Elisa Langa (Author)
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA
Antonio M.F. Palavra (Author)
INSTITUTO SUPERIOR TÉCNICO
Carlos A. Nieto de Castro (Author)
Dep. Química e Bioquímica
CQE
Ana M. Mainar (Author)

Resumo
The density, ρ, and two derived properties, isothermal compressibility, κT, and the coefficient of cubic expansion, αP, were obtained for the mixtures of 1-methyl-4-(1-methylethenyl)-cyclohexene, known as limonene, and (1S,5S)-6,6-dimethyl-2-methylenebibyclo[3.1.1]heptane, known as β-pinene, for nine different compositions and the pure components at five pressures from 20 MPa to 40 MPa and six temperatures from 283.15 K to 358.15 K. The experimental uncertainty for ρ, κT, and αP were respectively ±0.5 kg · m−3, ±14 TPa−1, and ±0.005 K−1, with k = 2 for all of them. Density behaviour with temperature and pressure was as expected. The values of αP and κT increase with temperature and decrease with increasing pressure. Two different equations of state, conventional SAFT and PC-SAFT, were applied to predict the densities of the mixture. The best predictions were achieved with PC-SAFT.


Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
The Journal of Chemical Thermodynamics

Identificadores da Publicação

Editora
Elsevier BV



Identificadores do Documento
DOI - https://doi.org/10.1016/j.jct.2011.12.013
URL - http://dx.doi.org/10.1016/j.jct.2011.12.013

Keywords
Alpha-Pinene Limonene Density SAFT PC-SAFT density mixtures terpenes

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