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Publication details

Document type
Journal articles

Document subtype
Full paper

Title
Asymmetric Carbon-Carbon Bond Forming Reactions Catalysed by Metal(II) Bis(oxazoline) Complexes Immobilized using Supported Ionic Liquids

Participants in the publication
P. Goodrich (Author)
C. Hardacre (Author)
C. Paun (Author)
A. Ribeiro (Author)
INSTITUTO SUPERIOR TÉCNICO
 S. Kennedy (Author)
M. J. V. Lourenço (Author)
Dep. Química e Bioquímica
 CQE
 H. Manyar (Author)
C. A. Nieto de Castro (Author)
Dep. Química e Bioquímica
 CQE
 M. Besnea (Author)
V. I. Pârvulescu (Author)

Summary
A series of bis(oxazoline) metal(II) complexes has been supported on silica and carbon supports by non?covalent immobilisation using an ionic liquid. The catalytic performance of these solids was compared for the enantioselective Diels–Alder reaction between N?acryloyloxazolidinone and cyclopentadiene and the Mukaiyama?aldol reaction between methyl pyruvate and 1?methoxy?1?trimethylsilyloxypropene. In both reactions the enantioselectivity was strongly influenced by the choice of support displaying enantioselectivies (ee values) up to 40% higher than those conducted under homogeneous reaction conditions.

Date of Publication
2011-04-13

Institution
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Where published
Advanced Synthesis & Catalysis

Publication Identifiers

Publisher
Wiley

Volume
353
Number
6

Number of pages
10
Starting page
995
Last page
1004

Document Identifiers
DOI - https://doi.org/10.1002/adsc.201000953
URL - http://dx.doi.org/10.1002/adsc.201000953

Keywords
asymmetric catalysis Diels–Alder reaction ionic liquids Mukaiyama-aldol reaction supported catalysts

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APA
P. Goodrich, C. Hardacre, C. Paun, A. Ribeiro, S. Kennedy, M. J. V. Lourenço, H. Manyar, C. A. Nieto de Castro, M. Besnea, V. I. Pârvulescu, (2011). Asymmetric Carbon-Carbon Bond Forming Reactions Catalysed by Metal(II) Bis(oxazoline) Complexes Immobilized using Supported Ionic Liquids. Advanced Synthesis & Catalysis, 353, 995-1004. http://dx.doi.org/10.1002/adsc.201000953

IEEE
P. Goodrich, C. Hardacre, C. Paun, A. Ribeiro, S. Kennedy, M. J. V. Lourenço, H. Manyar, C. A. Nieto de Castro, M. Besnea, V. I. Pârvulescu, "Asymmetric Carbon-Carbon Bond Forming Reactions Catalysed by Metal(II) Bis(oxazoline) Complexes Immobilized using Supported Ionic Liquids" in Advanced Synthesis & Catalysis, vol. 353, pp. 995-1004, 2011. 10.1002/adsc.201000953

BIBTEX
@article{51127, author = {P. Goodrich and C. Hardacre and C. Paun and A. Ribeiro and S. Kennedy and M. J. V. Lourenço and H. Manyar and C. A. Nieto de Castro and M. Besnea and V. I. Pârvulescu}, title = {Asymmetric Carbon-Carbon Bond Forming Reactions Catalysed by Metal(II) Bis(oxazoline) Complexes Immobilized using Supported Ionic Liquids}, journal = {Advanced Synthesis & Catalysis}, year = 2011, pages = {995-1004}, volume = 353 }