BIBLIOS

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
Thermochemistry of 1-bromoadamantane in binary mixtures of water–aprotic solvent

Participantes na publicação
Nelson Nunes (Author)
Filomena Martins (Author)
Dep. Química e Bioquímica
CQB
Ruben E. Leitão (Author)

Resumo
Solution enthalpies of 1-bromoadamantane in the mixed solvents water–N,N-dimetylformamide, water–N,N-dimethylacetamide and water–acetone were determined at 298.15 K, within the range of solubility of 1-bromoadamantane (1-BrAd) in the mixed solvents. The solution enthalpy of 1-bromoadamantane in water was determined based on extrapolation from the three mixtures. Enthalpies of transfer from the mixed solvents to cyclohexane were calculated. The effect of the composition of the mixtures on the thermochemical values obtained was also investigated


Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
Thermochimica Acta

Identificadores da Publicação

Editora
Elsevier BV



Identificadores do Documento
DOI - https://doi.org/10.1016/j.tca.2005.11.035
URL - http://dx.doi.org/10.1016/j.tca.2005.11.035

Identificadores de Qualidade
SCIMAGO Q2 (2006) - 0.572 - Physical and Theoretical Chemistry

Keywords
1-Bromoadamantane Mixtures Water Solution enthalpy