BIBLIOS

Document type
Journal articles

Document subtype
Full paper

Title
Solution Enthalpies of Hydroxylic Compounds: Study of Solvent Effects Through Quantitative Structure -Property Relationships

Participants in the publication
Marina Reis (Author)
Luís Moreira (Author)
Nelson Nunes (Author)
Ruben Leitão (Author)
Filomena Martins (Author)
Dep. Química e Bioquímica
CQB

Summary
Solution enthalpies of adamantan-1-ol, 2-methyl- butan-2-ol, and 3-methylbutan-1-ol have been measured at 298.15 K, in a set of 16 protogenic and non-protogenic solvents. The identification and quantification of solvent effects on the solution processes under study were performed using quantitative-structure property relationships. The results are discussed in terms of solute–solvent–solvent interactions and also in terms of the influence of compound’s size and position of its hydroxyl group.


Institution
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Where published
Journal of Thermal Analysis and Calorimetry

Publication Identifiers

Publisher
Springer Science and Business Media LLC



Document Identifiers
DOI - https://doi.org/10.1007/s10973-011-1975-x
URL - http://dx.doi.org/10.1007/s10973-011-1975-x

Rankings
SCIMAGO Q3 (2012) - 0.597 - Physical and Theoretical Chemistry
Web Of Science Q3 (2012) - 1.982 - Physical Chemistry

Keywords
QSPR Solution enthalpy Solvent effects Adamantan-1-ol 2-Methylbutan-2-ol 3-Methylbutan-1-ol