BIBLIOS

   Ciências References Management System

Visitor Mode (Login)
Need help?


Back

Publication details

Document type
Journal articles

Document subtype
Full paper

Title
Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines

Participants in the publication
Ekaterina S. Smirnova (Author)
José M. Muñoz?Molina (Author)
Alice Johnson (Author)
Nuno A. G. Bandeira (Author)
Carles Bo (Author)
Antonio M. Echavarren (Author)

Summary
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag) complexes is presented. The linear [AuI4] complex undergoes C−H functionalization of carbonyl compounds under mild reaction conditions. In addition, [AuI4AgI] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles.

Date of Publication
2016-05-11

Where published
Angewandte Chemie International Edition

Publication Identifiers
ISSN - 1433-7851

Publisher
Wiley

Volume
55
Number
26

Number of pages
4
Starting page
7487
Last page
7491

Document Identifiers
DOI - https://doi.org/10.1002/anie.201603200
URL - http://dx.doi.org/10.1002/anie.201603200

Rankings
SCIMAGO Q1 (2020) - 5.831 - Chemistry (miscellaneous)
Web Of Science Q1 (2020) - 15.336 - CHEMISTRY, MULTIDISCIPLINARY - SCIE


Export

APA
Ekaterina S. Smirnova, José M. Muñoz?Molina, Alice Johnson, Nuno A. G. Bandeira, Carles Bo, Antonio M. Echavarren, (2016). Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines. Angewandte Chemie International Edition, 55, 7487-7491. ISSN 1433-7851. eISSN . http://dx.doi.org/10.1002/anie.201603200

IEEE
Ekaterina S. Smirnova, José M. Muñoz?Molina, Alice Johnson, Nuno A. G. Bandeira, Carles Bo, Antonio M. Echavarren, "Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines" in Angewandte Chemie International Edition, vol. 55, pp. 7487-7491, 2016. 10.1002/anie.201603200

BIBTEX
@article{48908, author = {Ekaterina S. Smirnova and José M. Muñoz?Molina and Alice Johnson and Nuno A. G. Bandeira and Carles Bo and Antonio M. Echavarren}, title = {Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines}, journal = {Angewandte Chemie International Edition}, year = 2016, pages = {7487-7491}, volume = 55 }