BIBLIOS

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters

Participantes na publicação
Miguel A. Huertos (Author)
Israel Cano (Author)
Nuno A. G. Bandeira (Author)
Jordi Benet-Buchholz (Author)
Carles Bo (Author)
Piet W. N. M. van?Leeuwen (Author)

Resumo
The reaction of [CuI(HSC6H4PPh2)]2 with NaBH4 in CH2Cl2/EtOH led to air- and moisture-stable copper hydride nanoparticles (CuNPs) containing phosphinothiolates as new ligands, one of which was isolated by crystallization. The X-ray crystal structure of [Cu18H7L10I] (L=−S(C6H4)PPh2) shows unprecedented features in its 28-atom framework (18?Cu and 10?S atoms). Seven hydrogen atoms, in hydride form, are needed for charge balance and were located by density functional theory methods. H2 was released from the copper hydride nanoparticles by thermolysis and visible light irradiation.


Suporte
Chemistry - A European Journal

Identificadores da Publicação
ISSN - 0947-6539

Editora
Wiley



Identificadores do Documento
DOI - https://doi.org/10.1002/chem.201404763
URL - http://dx.doi.org/10.1002/chem.201404763

Identificadores de Qualidade
Web Of Science Q2 (2020) - 5.236 - CHEMISTRY, MULTIDISCIPLINARY - SCIE
SCIMAGO Q1 (2020) - 1.687 - Chemistry (miscellaneous)