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Detalhes Referência

Tipo
Artigos em Revista

Tipo de Documento
Artigo Completo

Título
Synthesis and properties of Polythionine/Co-doped titanate nanotubes hybrid materials

Participantes na publicação
Ferreira, Virginia C (Author)
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA
Dep. Química e Bioquímica
Dep. Química e Bioquímica
CQB
O.C. Monteiro (Author)
CQB

Resumo
tThe synthesis of polythionine (PTN)/cobalt-doped titanate nanotubes (CoTNTs) hybrid conducting filmswith distinct layouts, using electropolimerization, is reported. The CoTNTs nanocrystalline elongated particles were obtained by a hydrothermal treatment, using an amorphous Co-doped material as precursor. The adsorption ability of the prepared CoTNTs to remove organic dyes from aqueous media was investigated, using thionine (Th). The total amount of Th removed by the nanocrystalline CoTNTs powder was 340.06 mg g−1. During this process, and due to the CoTNTs structural properties, the combination of dye adsorption and intercalation was considered. After dye sensitization, the Th/CoTNTs were char-acterized and used for Th electropolymerization studies, in order to produce hybrid polythionine (PTN) electroactive films. The electroactivity of the Th molecules after immobilization in the CoTNTs surface is maintained. After electropolymerization, stable and electroactive nanostructured CoTNTs–PTN modified electrodes were obtained. The influence of the experimental parameters in the final electrical and morphological properties of the obtained hybrid films was studied, mainly the presence of the monomer in solution, adsorbed or intercalated in CoTNTs.

Data de Submissão/Pedido
2012-10-07
Data de Aceitação
2013-07-10
Data de Publicação
2013-07-22

Instituição
FACULDADE DE CIÊNCIAS DA UNIVERSIDADE DE LISBOA

Suporte
ELECTROCHIMICA ACTA

Identificadores da Publicação
ISSN - 0013-4686

Volume
113

Página Inicial
817
Página Final
824

Identificadores do Documento
URL - http://dx.doi.org/10.1016/j.electacta.2013.07.073
DOI - https://doi.org/10.1016/j.electacta.2013.07.073

Identificadores de Qualidade
SCIMAGO Q1 (2016) - 1.355 - Electrochemistry
SCOPUS Q1 (2012) - 1.651 - Electrochemistry
Web Of Science Q1 (2017) - 5.116 - ELECTROCHEMISTRY - SCIE

Keywords
Cobalt doped titanate nanotubes Thionine Electro-polymerization Conducting hybrid films

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APA
Ferreira, Virginia C, O.C. Monteiro, (2013). Synthesis and properties of Polythionine/Co-doped titanate nanotubes hybrid materials. ELECTROCHIMICA ACTA, 113, 817-824. ISSN 0013-4686. eISSN . http://dx.doi.org/10.1016/j.electacta.2013.07.073

IEEE
Ferreira, Virginia C, O.C. Monteiro, "Synthesis and properties of Polythionine/Co-doped titanate nanotubes hybrid materials" in ELECTROCHIMICA ACTA, vol. 113, pp. 817-824, 2013. 10.1016/j.electacta.2013.07.073

BIBTEX
@article{25211, author = {Ferreira, Virginia C and O.C. Monteiro}, title = {Synthesis and properties of Polythionine/Co-doped titanate nanotubes hybrid materials}, journal = {ELECTROCHIMICA ACTA}, year = 2013, pages = {817-824}, volume = 113 }